Journal
DALTON TRANSACTIONS
Volume 41, Issue 4, Pages 1158-1164Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1dt11065a
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Complexation of a rigid multi-pyridine ligand bis(2-pyridyl)-1,8-naphthyridine (bpnp) with [Cu-2(TFA)(4)] (TFA = trifluoroacetate) resulted in the formation of a dinuclear copper(II) complex, namely [Cu-2(bpnp)(mu-OH)(TFA)(3)] (1). This complex has been characterized by X-ray crystallographic, spectroscopic and elemental analyses. Complex 1 is an efficient catalyst for the oxidative coupling of various 2,6-disubstituted phenols with molecular oxygen. Yields and selectivity depend on the reaction conditions employed, the best results being obtained in isopropanol or dioxane at 90 degrees C with yields of >99%. Mechanistic pathway of the catalysis is discussed.
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