4.7 Article

Ytterbium can relax slowly too: a field-induced Yb2 single-molecule magnet

Journal

DALTON TRANSACTIONS
Volume 41, Issue 40, Pages 12349-12352

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt31677c

Keywords

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Funding

  1. NSFC of China [21102039, 21072049]
  2. NSFC of Heilongjiang Province [10td03]
  3. NSERC-DG
  4. CFI
  5. ORF
  6. ERA Canada

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An unusual dinuclear Yb-2 complex isolated using a mixed ligand strategy leads to field-induced SMM behaviour. Low magnetic axiality and a large tunnelling gap lead to significant quantum tunnelling of the magnetisation, which was reduced under an applied static optimum field of 1600 Oe.

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