4.7 Article

Auxiliary ligand induced structural allomorphism in nanotubular microporous metal-organic frameworks based on discrete magnesium clusters

Journal

DALTON TRANSACTIONS
Volume 41, Issue 8, Pages 2231-2233

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt11872f

Keywords

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Funding

  1. NNSF of China [21001022, 21171033]
  2. National Grand Fundamental Research 973 Program of China [2010CB635114]
  3. Program for New Century Excellent Talents in Chinese University [NCET-10-0282]
  4. Science and Technology Development Planning of Jilin Province [201001169]
  5. Fundamental Research Funds for the Central Universities [09QNJJ018, 09ZDQD003, 10CXTD001]

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Three allomorphs with the same stoichiometry, [Mg-3(H2O)(4)(5-aip)(2)(5-Haip)(2)]center dot 4DMA, were solvothermally synthesized in the presence of different additives and represented the first 8-connected nanotubular networks in Mg-based metal-organic frameworks. The adsorption and delivery of drugs were also determined.

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