Journal
DALTON TRANSACTIONS
Volume 41, Issue 17, Pages 5368-5376Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt12483a
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Funding
- University of Bonn
- COST action [cm0802]
- National Science Foundation [CHE-0413521, CHE-0115760]
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Selective formation of 4-phosphanylated 1,2-dialkyl imidazole-2-thiones 3a-f has been obtained via a lithiation followed by phosphanylation reaction. The reactivity of 3a-f was examined towards oxidation and complexation reactions. All products were unambiguously characterized by elemental analyses, spectroscopic and spectrometric methods including X-ray analysis (3a, 3b, 4b, 4d, 5b, 6a and 6d).
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