Journal
DALTON TRANSACTIONS
Volume 41, Issue 30, Pages 9019-9022Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30384a
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Funding
- Imperial College
- EPSRC [EP/P505550/1]
- Royal Society [RG100606]
- Royal Commission for the Exhibition of 1851
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Tris[3,5-bis(trifluoromethyl)phenyl]borane (1, BArF18), has been synthesised on a practical scale for the first time. According to the Gutmann-Beckett method it is a more powerful Lewis acid than B(C6F5)(3). It forms a 'frustrated Lewis pair' with 2,2,6,6-tetramethylpiperidine which cleaves H-2 to form a salt containing the novel anion [mu-H(BArF18)(2)](-).
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