4.7 Article

Orientations of polyoxometalate anions on gold nanoparticles

Journal

DALTON TRANSACTIONS
Volume 41, Issue 33, Pages 9849-9851

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30592e

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Funding

  1. ISF [248/09, 1667/09, 1720/08, 948/10]

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Cryogenic transmission electron microscopy of polyoxometalate-protected gold nanoparticles reveals that the Preyssler ion, [NaP5W30O110](14-), lies face down with its C-5 axis perpendicular to the gold surface, while the Finke-Droege ion, [P4W30Zn4(H2O)(2)O-112](16-), is tilted, with its long axis close to 60 degrees from the normal to the surface.

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