Journal
DALTON TRANSACTIONS
Volume 41, Issue 18, Pages 5458-5460Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30174a
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- Defense Advance Research Projects Agency [HR0011-10-C-0052]
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Sodalite zeolitic imidazolate frameworks containing Co (ZIF-67) and Zn (ZIF-8) were synthesized at room temperature under aqueous conditions in 10 min. A trialkylamine deprotonated the 2-methylimidazole ligand and nucleated the frameworks. Furthermore, the ligand acted as a structure directing agent in place of an organic solvent.
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