Journal
DALTON TRANSACTIONS
Volume 41, Issue 38, Pages 11783-11787Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30920c
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Funding
- Chinese Academy of Sciences [KJCX2-YW-319, KJCX2-EW-H01]
- MOST [2010CB933501, 2012CB821705]
- National Natural Science Foundation of China
- Natural Science Foundation of Fujian Province [2007HZ0001-1, 2009HZ0004-1, 2009HZ0005-1, 2009HZ0006-1, 2006L2005]
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Two polyoxometalate-pillared 3D compounds, {Cu-5(2-ptz)(6)(H2O)(4)(SiW12O40)}center dot 4H(2)O 1 and {Cu-9(2-ptz)(12)(H2O)(6)(PMo12O40)(2)}center dot H2O 2 (2-ptz = 5-(2-pyridyl) tetrazole) have been constructed based on different polyoxometalate anions, and copper-organic coordination polymer sheets by a hydrothermal method. Magnetic investigations reveal that both 1 and 2 exhibit antiferromagnetic coupling between the Cu-II ions. Structural studies show the compound 1 exhibits a typical pcu-type net with the Schalfli symbol of {4(12).6(3)}, and that compound 2 is a (3,4,6)-connected framework with novel {4(4).6(10).10}{6(3)}(2){6(5).8} topology which has not been reported to date.
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