4.7 Article

Improvement of blue, white and NIR emissions in YPO4:Dy3+ nanoparticles on co-doping of Li+ ions

Journal

DALTON TRANSACTIONS
Volume 41, Issue 45, Pages 13810-13814

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt32062b

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Funding

  1. University Grants Commission (UGC) [F.4-2/2006(BSR)/13-309/2008(BSR)]

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As-prepared samples of YPO4:2Dy nanoparticles prepared by polyol route show strong blue luminescence because of strong host contribution, whereas 500 and 900 degrees C annealed samples show cold and warm white luminescence, respectively because of different energy transfer rates from host to Dy3+. Li+ co-doping improves luminescence intensity as well as crystallinity significantly. Interestingly, Li+ ions occupy interstitial sites of lattice. These materials will be potential candidates for white light emitting diodes and near-infrared emitting phosphors.

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