Journal
DALTON TRANSACTIONS
Volume 41, Issue 38, Pages 11745-11752Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt31553j
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Funding
- Research Council of the University of Isfahan
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New hybrid complexes based on covalent interaction between 5,10,15,20-tetrakis(4-aminophenyl)porphyrinatozinc(II) and 5,10,15,20-tetrakis(4-aminophenyl)porphyrinatotin(IV) chloride, and a Lindqvist-type polyoxometalate, Mo6O192-, were prepared. These new porphyrin-polyoxometalate hybrid materials were characterized by H-1 NMR, FT IR and UV-Vis spectroscopic methods and cyclic voltammetry. These spectro- and electrochemical studies provided several spectral data for synthesis of these compounds. Cyclic voltammetry showed the influence of the polyoxometalate on the redox process of the porphyrin ring. The catalytic activity of tin(IV)porphyrin-hexamolybdate hybrid material was investigated in the acetylation of alcohols and phenols with acetic anhydride. The reusability of this catalyst was also investigated.
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