4.7 Article

Synthetic routes to [Au(NHC)(OH)] (NHC = N-heterocyclic carbene) complexes

Journal

DALTON TRANSACTIONS
Volume 41, Issue 18, Pages 5461-5463

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30294b

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Funding

  1. ERC
  2. EPSRC
  3. Engineering and Physical Sciences Research Council [EP/J011053/1] Funding Source: researchfish
  4. EPSRC [EP/J011053/1] Funding Source: UKRI

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New procedures for the synthesis of [Au(NHC)(OH)] are reported. Initially, a two-step reaction via the digold complex [{Au(NHC)}(2)(mu-OH)][qBF(4)] was probed, enabling the preparation of the novel [Au(SIPr)(OH)] complex and of its previously reported congener [Au(IPr)(OH)]. After further optimization, a one-step procedure was developed.

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