4.7 Article

Cooperation between metal and ligand in oxygen atom transport by N-confused porphyrin oxorhenium(V) complexes

Journal

DALTON TRANSACTIONS
Volume 41, Issue 30, Pages 9154-9157

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30885a

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Funding

  1. MEXT [22350020, 22655044]
  2. Grants-in-Aid for Scientific Research [22350020] Funding Source: KAKEN

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N-Confused porphyrin oxorhenium(V) complexes were prepared and their X-ray structures were elucidated. The oxorhenium(V) complexes can transfer oxygen atom from pyridine N-oxide to triphenylphosphine, in which unique cooperation between metal and ligand was observed.

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