Journal
DALTON TRANSACTIONS
Volume 41, Issue 36, Pages 10934-10937Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt31401k
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Funding
- CNRS
- French Ministry for Research
- Institut Universitaire de France
- ANR program [09-Blanc-0101-01]
- Chinese Scholarship Council
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The reaction of [RuCl2(p-cymene)](2) with arylimines and 4 equiv. of KOAc in methanol at room temperature produces stable ((NC)-C-boolean AND)-cyclometallated ruthenium(II) complexes via C-H bond activation/deprotonation. This method can be applied also to nitrogen-containing molecules: N-phenylpyrazole, 2-phenyl-2-oxazoline and benzo[h]quinoline. N-Phenylpyrazole, [RuCl2(p-cymene)](2) and diphenylacetylene directly lead to alkyne insertion into the metallacycle C-Ru bond.
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