Journal
DALTON TRANSACTIONS
Volume 40, Issue 41, Pages 10812-10814Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1dt11241d
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Funding
- EPA [2008-ET-MS-3-S2]
- SFI [07/SRC/B1160, 08/RFP/CHE1349]
- Netherlands Organisation for Scientific Research
- German Research Association (DFG) [DFG SFB 583, GRK 1626]
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A pyrazine bridged ruthenium/palladium bimetallic photocatalyst with peripheral 4,4'-dicarboxyethyl-2,2'-bipyridine ligands, EtOOC-RuPd, is reported, together with its 2,2'-bipyridine analogue. Upon irradiation with visible light, EtOOC-RuPd catalyses the production of hydrogen gas whereas the complex RuPd does not.
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