4.7 Article

Bimetallic aluminum alkyl complexes as highly active initiators for the polymerization of epsilon-caprolactone

Journal

DALTON TRANSACTIONS
Volume 40, Issue 43, Pages 11378-11381

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1dt11380a

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Funding

  1. National Natural Science Foundation of China [20972108, 21174095, 21132002]
  2. PAPD
  3. Qing Lan Project

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Two dinuclear aluminum alkyl complexes supported by a piperazidine-bridged bis(phenolato) group were prepared, and both complexes exhibited extremely high activity for the ring-opening polymerization of epsilon-caprolactone. In the presence of benzyl alcohol (BnOH), the polymerization accelerated dramatically.

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