Journal
DALTON TRANSACTIONS
Volume 40, Issue 38, Pages 9795-9801Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1dt11036e
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Funding
- HHMI Undergraduate Science Education Award [52005907]
- National Science Foundation [CHE-0629136, CHE-0741973, CHE-0639239, CHE-0847763]
- Welch Foundation [F-1631]
- Petroleum Research Fund administered by the American Chemical Society [47022-G3]
- American Heart Association [0765078Y]
- UT-CNM and UT-Austin
- Hong Kong Baptist University [FRG/06-07/II-16]
- Hong Kong Research Grants Council [HKBU 202407]
- Division Of Chemistry [0741973, 0847763] Funding Source: National Science Foundation
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Three new lanthanide 1-D coordination polymers ({[Ln(2)(H2L)(OAc)(6)]center dot EtOH center dot 2H(2)O}(n) (Ln = Eu (1), Er (2)) and {YbNiLCl(OAc)(2)(H2O)}(n) (3)) and a heterobinuclear complex [YbNiLCl3(H2O)(3)] (4) are reported which are formed from salen type Schiff-base ligands H2L (H2L = N,N'-bis(3-methoxysalicylidene) butane-1,4-diamine). The polymeric structures are formed by bridging H2L units in the case of 1 and 2, and by acetate groups in 3. The structures of 1-4 were determined by single crystal X-ray crystallographic studies and their luminescence properties in MeCN solution were determined.
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