4.7 Article

A novel detection of hydrogen peroxide based on a luminescent polyoxometalate

Journal

DALTON TRANSACTIONS
Volume 40, Issue 19, Pages 5298-5301

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1dt10259a

Keywords

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Funding

  1. National Natural Science Foundation of China [21073076]
  2. National Basic Research Program of China [2007CB808003]
  3. Technology of Jilin Province, China [201115016]
  4. Jilin University [20111019]
  5. State Key Laboratory of Electroanalytical Chemistry of the Chinese Academy of Sciences, CAS [SKLEAC2010002]

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In this paper, we attempt to construct a simple and sensitive detection method for hydrogen peroxide based on reversible colour change and luminescence switching modulated by the electrochemical stimulation and redox reaction of H2O2 with electroreduced polyoxometalate. This method successfully combines the electrochromic and luminescent properties of the polyoxometalate to develop a novel detection method for H2O2 with good reversibility, which displays high sensitivity, a wide linear range and a low detection limit to H2O2.

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