Journal
DALTON TRANSACTIONS
Volume 40, Issue 45, Pages 12048-12051Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1dt11195g
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Funding
- DST [SR/S1/IC-01/2008]
- CSIR, New Delhi, India [01-2235/08/EMR-II]
- IIT Guwahati, India
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The tris(thiourea) receptor, L, in the presence of excess H2PO4- has been found to encapsulate a trivalent phosphate ion within a pi-stacked dimeric capsular assembly of the receptor with twelve strong H-bonds via deprotonation, as evident from the origin of a new set of signals in the (HNMR)-H-1 titration experiments.
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