Journal
DALTON TRANSACTIONS
Volume 40, Issue 11, Pages 2429-2432Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt01326a
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- National Science Foundation [CHE-719157]
- NSERC
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Facile methoxymethylation of N-2-derived nitride NMo(N-[Bu-t]Ar)(3) provided the imido cation [MeOCH2NMo(N-[Bu-t]Ar)(3)](+) as its triflate salt in 88% yield. Treatment of the latter with LiN(SiMe3)(2) provided blue methoxyketimide complex MeO(H)CNMo(N[Bu-t]Ar)(3) in 95% yield. Conversion of the latter to the terminal cyanide complex NCMo(N[Bu-t]Ar)(3), which was the subject of a single-crystal X-ray diffraction study, was accomplished in 51% yield upon treatment with a combination of SnCl2 and Me2NSiMe3.
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