Journal
DALTON TRANSACTIONS
Volume 40, Issue 44, Pages 11937-11940Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1dt11592h
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Funding
- National Natural Science Foundation of China [20725205]
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Reactions of the aminochlorosilane RSiHCl2 and disilane R2Si2HCl3 (R = (2,6-iPr(2)C(6)H(3))(SiMe3)N) with an excess of 1,3-bis(tert-butyl)imidazol-2-ylidene resulted in the silylation of the NHC while reaction with the less hindered 1,3-diisopropyl-4,5-dimethyl-imidazol-2-ylidene yielded an NHC-stabilized aminochlorosilylene.
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