Journal
DALTON TRANSACTIONS
Volume 40, Issue 20, Pages 5458-5463Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt01675f
Keywords
-
Categories
Funding
- Deutsche Forschungsgemeinschaft [1178]
Ask authors/readers for more resources
A stable silicon(II) monohydride is accomplished through a covalent shared interaction of the silylene lone-pair and a sp(3)-hybridized boron atom of the Lewis acidic BH(3). Experimental charge density investigations reveal a central positively charged silicon atom bound to a negatively charged hydrogen atom. The positively charged H-Si-BH(3) moiety is coordinated by the lone-pairs of electrons of the benzamidinate ligand. This coordination is reinforced by a transannular Si1 center dot center dot center dot C1 privileged exchange channel.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available