Journal
DALTON TRANSACTIONS
Volume 40, Issue 32, Pages 8086-8088Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1dt11144b
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Funding
- Natural Sciences and Engineering Council of Canada
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The metathetical reactions of Li-2[C(Ph2PS)(2)] with MCl3 (M = Sb, Bi) in a 1:1 molar ratio in toluene afford the complexes {MCl[C(Ph2PS)(2)]}(2), which dimerise through weak M center dot center dot center dot S interactions; the S,C,S-coordination of the tridentate ligand to the metal in themonomeric units incorporates a polar M-C single bond and a three-centre two-electron S-M-S bond.
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