Journal
DALTON TRANSACTIONS
Volume 40, Issue 35, Pages 9020-9025Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1dt10287g
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- US National Science Foundation [CHE-0848248]
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The addition of 2,6-dimethylphenyl isocyanide (CN[DMeP], two equivalents) to previously reported (PNP) Sc(III) pyridyl complexes resulted in the formation of novel indoline complexes of scandium. By varying the nature of the pyridyl moiety one can intercept an intermediate prior to methyl migration. In addition to structural studies of two indolene complexes, we also propose a mechanism for the insertion and indolene ring closure.
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