Journal
DALTON TRANSACTIONS
Volume 40, Issue 39, Pages 10237-10241Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1dt10070j
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Funding
- NNSFC [20825103, 90922031, 21021061]
- MSTC [2007CB815304]
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Three metal-organic frameworks, [M-3(ip)(4)][EMIm](2) (M = Co 1, Ni 2, Mn 3, H(2)ip = isophthalic acid, EMIm = 1-ethyl-3-methyl imidazolium) were prepared from an ionic liquid medium. All the compounds feature the same (4(24))(6(4)) topology based on linear trinuclear clusters as eight-connected nodes. Compounds 1 and 2 are isostructural, while compound 3 exhibits a different structure due to the slight difference in the arrangement of M-3(OOCR)(8) SBUs. Magnetic property measurements reveal that all the compounds display anti-ferromagnetic coupling, where compounds 2 and 3 show isotropic exchange interactions of -0.10 cm(-1) for 2 and -1.6 cm(-1) for 3. Investigation of the thermal diffusivity shows that the thermal diffusivity of 1 is higher than that of 3, while that of 3 is higher than that of 2.
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