4.7 Article

Mechanistic analysis of trans C-N reductive elimination from a square-planar macrocyclic aryl-copper(III) complex

Journal

DALTON TRANSACTIONS
Volume 40, Issue 35, Pages 8959-8963

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1dt10463b

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Funding

  1. US Department of Energy [DE-FG02-05ER15690]
  2. Bristol-Myers Squibb

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A net trans C-N reductive elimination reaction is observed from a macrocyclic aryl-Cu-III complex, and a mechanistic study of this reaction indicates that coordinating ligands play a role in mediating this unusual transformation.

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