Journal
DALTON TRANSACTIONS
Volume 40, Issue 16, Pages 4324-4331Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt01765e
Keywords
-
Categories
Funding
- EPSRC
- Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]
- Royal Society
- Engineering and Physical Sciences Research Council [EP/F021925/1] Funding Source: researchfish
- EPSRC [EP/F021925/1] Funding Source: UKRI
Ask authors/readers for more resources
An exploratory study of the synthesis of vanadium (oxy)fluorides (VOFs) using ionic liquids (ILs) and deep eutectic mixtures (DESs) as a solvent yielded 10 different materials. The previously reported chain type: (NH(4))(2)VF(5) (1), (NH(4))(2)VOF(4) (2), NH(4)VO(3) (3) and (H(2)NH(2)(CH(2))(2)NH(2))VF(5) (9) have been successfully produced for the first time using ILs as the reaction media. The monomeric (HNH(2)CH(3))(2)VOF(4)(H(2)O) (4), the dimer (HNH(2)CH(3))(4)V(2)O(2)F(8) (5) and the 1D chains (HNH(2)CH(3))(2)VF(5) (6), (H(2)O)(2)VF(3) (7), alpha-(H(2)NH(2)(CH(2))(2)NH(2))VOF(4) (8) and beta-(H(2)NH(2)(CH(2))(2)NH(2)) VOF(4) (10) are novel materials. Template control has also been achieved by the selective choice of ILs or the appropriate deep eutectic mixture, where the expected template is delivered to the reaction by the partial breakdown of the urea derivative portion of the DES.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available