Journal
DALTON TRANSACTIONS
Volume 40, Issue 12, Pages 2716-2719Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt01768j
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- Swiss National Science Foundation
- COST [D40]
- European Research Council
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Main-chain C,N-protected histidine has been successfully alkylated at both side-chain nitrogens. The corresponding histidinium salt was metallated with ruthenium(II) by a transmetalation procedure, thus providing histidine-derived NHC ruthenium complexes. These bio-inspired comsxsxsplexes show appreciable activity in the catalytic transfer hydrogenation of ketones.
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