Journal
DALTON TRANSACTIONS
Volume 40, Issue 10, Pages 2177-2179Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt01645d
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- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan [471]
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A photoreactive rhodium dithionite complex [(RhCpEt)(2)(mu-CH2) (2)(mu-O2SSO2)] (1(Et)) with Cp-Et (eta(5)-C5Me4Et) ligands was newly synthesized. Upon short-time irradiation with low intensity light, two kinds of stepwise surface morphology changes of the crystal 1(Et) were observed. Prolonged irradiation with high intensity light caused cracking and breaking down of the crystal.
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