Journal
DALTON TRANSACTIONS
Volume 40, Issue 10, Pages 2338-2347Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt00950d
Keywords
-
Categories
Funding
- NEDO GSC
- Inoue Foundation for Science
- JCII Subsidy System for Advanced Innovation in Chemical Industry in Japan
Ask authors/readers for more resources
Molecularly imprinted Ru-complex catalysts acting in water were prepared on a SiO2 surface by molecular imprinting of a SiO2-supported Ru-complex using organic polymers as surface matrix overlayers. (R)-1-(o-fluorophenyl) ethanol, which is one of the hydrogenated products of o-fluoroacetophenone, was imprinted on the supported Ru-complex as a template, and an active Ru-complex with a shape-selective reaction space (molecularly imprinted cavity) was prepared inside the wall of the hydrophobic organic polymer matrix overlayers. Structures of the SiO2-supported and molecularly imprinted Ru catalysts were characterized by means of solid-state NMR, XPS, XRF, ICP, UV/vis, XAFS, TGA, and SEM. The molecularly imprinted Ru catalysts exhibited fine shape selectivity and enantioselectivity for the asymmetric transfer hydrogenation of o-fluoroacetophenone and its derivatives.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available