Journal
DALTON TRANSACTIONS
Volume 40, Issue 6, Pages 1387-1395Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt01183e
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Funding
- Ministere de la Recherche (France)
- CNRS (France)
- Ministerio de Educacion y Ciencia [CTQ2007-61901/BQU, CTQ2006-15672-C05-03]
- Comunidad Autonoma de Madrid [S-0505/PPQ/0225]
- Ministere de l'Education Nationale, de la Recherche et de la Technologie (France)
- LONZA AG (Switzerland)
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A series of new triazolopyridine-based phosphines has been prepared. These compounds revealed unexpected spectroscopic patterns. In particular, the NMR spectra are highly dependent on the relative conformational preference of the phosphine substituent at C7. Here, we report on their complete NMR analysis, X-ray structures and DFT calculations that confirm the particular arrangement of the phosphorus lone pair orbital related to the substituent pattern of the chosen phosphine.
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