Journal
DALTON TRANSACTIONS
Volume 40, Issue 15, Pages 3802-3804Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt01826k
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The catalytic activity of [Ru(tpy)(bpy)OH2](2+) (tpy = 2,2': 6', 2 ''-terpyridine and bpy = 2,2'-bipyridine) increased by a 4'-substituted ethoxy group on the tpy ligand by more than one order of magnitude to give 1.1 x 10(-1) s(-1) of catalyst turnover frequency, which is comparable with the hitherto-reported champion data.
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