Journal
DALTON TRANSACTIONS
Volume 40, Issue 19, Pages 5259-5270Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1dt10160a
Keywords
-
Categories
Funding
- Ministero dell'Istruzione, dell'Universita e della Ricerca (MiUR) [2007WJMF2W]
Ask authors/readers for more resources
Four cyclometalated Pt(IV) compounds, 1a,b and 2a,b, were successfully obtained by oxidative addition of I(2) to 2-phenylpyridinate (PhPy) and Nile Red (NR) derived Pt(II) complexes with acetylacetonate (acac) or hexafluoroacetylacetonate (hacac) ancillary ligands. Single crystal X-ray diffraction, electrochemical, photophysical and computational studies have been performed in comparison with the analogues Pt(II) compounds, shedding new light on the role of the oxidation state of the metal centre towards both the luminescence properties and the dioxygen quenching.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available