Journal
DALTON TRANSACTIONS
Volume 39, Issue 29, Pages 6841-6846Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c002440f
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Funding
- National Science Foundation of the United States
- American Chemical Society
- Seaborg Institute (Los Alamos National Laboratory)
- LANL LDRD office
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The preparation of a family of bis(imido) uranium(VI) complexes stabilized by mono- and bidentate pyrrolyl ancillary ligands is described. X-ray crystallographic studies of dipyrrolylmethane (dpm) derivatives show that the pyrrolyl coordination mode in these uranium(VI) ions is unexpected in comparison to analogous transition metal and lanthanide chemistry. The ability of the coordinated pyrrolyl moieties to undergo pyrrolyl isomerization has also been explored and demonstrates reactivity that is unique from structurally similar uranium(VI)-bis(cyclopentadienyl) derivatives.
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