Journal
DALTON TRANSACTIONS
Volume 39, Issue 47, Pages 11375-11382Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt00895h
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Funding
- QUILL
- QUILL, Industrial Advisory Board
- EPSRC [EP/D029538/1]
- Engineering and Physical Sciences Research Council [EP/D029538/1] Funding Source: researchfish
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The Gutmann Acceptor Number (AN), which is a quantitative measure of Lewis acidity, has been estimated using the P-31 NMR chemical shift of a probe molecule, triethylphosphine oxide, for a range of chlorometallate(III) ionic liquids, based on Group 13 metals (aluminium(III), gallium(III) and indium(III)) and the 1-octyl-3-methylimidazolium cation, at different compositions. The results were interpreted in terms of extant speciation studies of chlorometallate(III) ionic liquids, and compared with a range of standard molecular solvents and acids. The value of these data were illustrated in terms of the selection of appropriate ionic liquids for specific applications.
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