Journal
DALTON TRANSACTIONS
Volume 39, Issue 37, Pages 8796-8800Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c001689f
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Funding
- Spanish Ministry of Science and Innovation (MICINN) [CTQ2008-06790, CTQ2007-60494/BQU]
- Regional Government of Andalucia [P06-FQM-01726, P07-FQM-3213, FQM339]
- University of Granada
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The H-atom transfer (HAT) from water to ketyl radicals, mediated by titanocene(III) aqua-complexes, can explain the TiIII-promoted reduction of ketones in aqueous medium better than the conventional House mechanism. Moreover, we also report novel evidences supporting the existence of these titanocene(III) aqua-complexes.
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