4.7 Article

A tetranuclear cobalt(II) chain with slow magnetization relaxation

Journal

DALTON TRANSACTIONS
Volume 39, Issue 45, Pages 10827-10829

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt00935k

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Funding

  1. Excellence Initiative of the German federal government
  2. Excellence Initiative of the German state government
  3. NSFC [2007CB815302, 90922031]

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A solvothermally derived tetranuclear cobalt(II) complex, [Co(4)(phen)(4)Cl(8)] (phen = phenanthroline), featuring a zig- zag backbone of {Co(mu(2)-Cl)(2)Co} planes, exhibits ferromagnetic exchange and slow relaxation of the magnetization and represents the first Co SMMwith a linear core structure.

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