Journal
DALTON TRANSACTIONS
Volume 39, Issue 24, Pages 5595-5604Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b924088h
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High-valent vanadium complexes bearing a variety of chelating aryloxides including di- and linear tri-phenolates, C/N-capped tripods, phenoxyimines and calixarenes type ligands, when used in combination with dialkylaluminium halides as co-catalyst and a reactivator, are found to act as highly active catalytic systems for alpha-olefin polymerisation. Pro-catalyst structure-catalytic activity trends can be identified for the various ligand families employed.
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