4.7 Article

Homogeneous photocatalytic production of hydrogen from water by a bioinspired [Fe2S2] catalyst with high turnover numbers

Journal

DALTON TRANSACTIONS
Volume 39, Issue 5, Pages 1204-1206

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b923159p

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Funding

  1. National Natural Science Foundation China [20633020]
  2. National Basic Research Program of China [2009CB220009]
  3. Program for Changjiang Scholars and Innovative Research Team in University [IRT0711]
  4. Swedish Energy Agency
  5. Swedish Research Council
  6. K & A Wallenberg Foundation

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A three-component homogeneous catalyst system, composed of a cyclometalated iridium(III) photosensitizer, a bioinspired diiron complex, and TEA in aqueous acetone, proved to be catalytically active for photoinduced H-2 production, with up to 660 turnovers over 8 h of irradiation.

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