Journal
DALTON TRANSACTIONS
Volume 39, Issue 43, Pages 10401-10413Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt00283f
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Funding
- Institut de Chimie des Substances Naturelles [ANR-08-BLAN-0013-01]
- COST Action [D40]
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Stereoselective catalytic intermolecular C-H amination of complex molecules is reported. Site-selective functionalizations occur with very good yields up to 91% and excellent d.e.s up to 99%. However, the precise nature of the nitrene C-H insertion remains a matter of debate despite several physical organic experiments.
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