Journal
DALTON TRANSACTIONS
Volume 39, Issue 7, Pages 1719-1721Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b914330k
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Funding
- MEXT (Ministry of Education, Culture, Sports, Science and Technology)
- Research Center for Materials with Integrated Properties, Toho University
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A new spin crossover (SCO) coordination polymer, {[Fe-II(4-methylpyridine)(2)][Au-I(CN)(2)](2)}(n) (1) has been synthesized. The complex (1) has been observed to have a thermal induced three-step SCO transition, which is unprecedented behavior as compared with existing SCO complexes. In the complex, about 18%, 41% and 41% high spin states are changed to low spin states in the first-step, second-step and third-step, respectively.
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