Journal
DALTON TRANSACTIONS
Volume 39, Issue 1, Pages 180-184Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b908424j
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- Universite de Strasbourg
- C.N.R.S.
- Institut Universitaire de France
- Ministere de l'Enseignement Superieur et de la Recherche
- Dutch Polymer Institute (DPI) [628]
- European Commission (EC) [MRTN-CT-2006-035884]
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A series of complexes based on the combination of cyclometallated palladium or platinum moieties with functionalized dipyrrin ligands bearing mesityl- or benzonitrile groups have been prepared and characterized both in the solid state and in solution; these compounds exhibit a characteristic dipyrrin-centered luminescence with an emission intensity modulated by the degree of rotational freedom of the aromatic group attached to the dipyrrin chelate.
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