Journal
DALTON TRANSACTIONS
Volume 39, Issue 40, Pages 9570-9578Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt00179a
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Funding
- National Natural Science Foundation of China [20973096, 20673060]
- National Basic Research Program of China [2009CB623502]
- Specialized Research Fund for the Doctoral Program of Higher Education [20070055014]
- Natural Science Foundation of Tianjin [08JCZDJC21500]
- Supporting Program for New Century Excellent Talents [NCET-06-0215]
- Nankai University
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Periodic mesoporous titanium phosphonate spheres are prepared in the presence of surfactant Brij 56 by utilizing sodium salt of ethylene diamine tetra(methylene phosphonic acid) as the coupling molecule. The spherical morphology could be only obtained with the water-ethanol ratio of 75/25. The synthesized hybrids possess periodic mesoporosity with specific surface area of 606 m(2) g(-1) and irregular macrovoids throughout the microspheres, revealed by the measurements of X-ray diffraction, nitrogen adsorption, scanning and transmission electron microscopy. The structure and chemical states of the materials are characterized by chemical analysis, FT-IR, MAS NMR, XPS and thermogravimetric analysis, indicating the homogeneous integrity of organic groups inside the hybrid framework, which allows Cu2+ ions extensively coordinated with these organic ligands. The monolayer adsorption behavior of Cu2+ ions is confirmed, and further calcination of the Cu2+ ion-dispersed matrix results in the highly dispersed CuO active components on the pore surface of mesoporous titanium phosphonates. The H-2-TPR analysis and catalytic CO oxidation testing prove that the CuO nanoparticles, dispersed on either hybrid or inorganic supports, prepared by this coordination and calcination strategy, possess high oxidation activity, making them promising catalysts for potential environmental applications.
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