4.7 Article

Chelated orthoborate ionic liquid as a reactant for the synthesis of a new cobalt borophosphate containing extra-large 16-ring channels

Journal

DALTON TRANSACTIONS
Volume 39, Issue 44, Pages 10571-10573

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt00368a

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Funding

  1. National Natural Science Foundation of China [20901076]
  2. Ministry of Education of China
  3. Natural Science Foundation of Liaoning Province, China [20092174]

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1-Ethyl-3-methylimidazolium bis(oxalato)borate ([Emim]-[BOB]), a room-temperature ionic liquid, has been prepared and used for the first time to develop new borate-containing material. A new open-framework cobalt borophosphate, (NH(4))(7)Co(4)(H(2)O)[B(2)P(4)O(15)(OH)(2)](2)[H(2)PO(4)][HPO(4)], with peanut shaped extra-large 16-ring channels has been obtained.

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