4.7 Article

Synthesis and comparative anion binding profiles of two di-aqua Eu(III) complexes

Journal

DALTON TRANSACTIONS
Volume 39, Issue 41, Pages 9897-9903

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt00773k

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Funding

  1. Bracco Imaging
  2. CISbio

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Two di-aqua Eu(III) complexes of heptadentate ligands are reported that show differing reactivity profiles towards various anions; a cationic complex with two azaxanthone moieties exhibits pronounced selectivity towards bicarbonate with an affinity constant, logK = 2.65 (295 K, 0.1 M NaCl).

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