Journal
DALTON TRANSACTIONS
Volume 39, Issue 8, Pages 2016-2022Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b921729k
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Funding
- CNRS/JSPS [PRC 450]
- ECOS CONICYT [C08E01]
- ANR [ANR-08-BLAN0105-01]
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The germene Mes(2)Ge=CR2 1 (Mes = 2,4,6-trimethylphenyl, CR2 = fluorenylidene) reacts with 5-methoxy-1,4-naphthoquinone to yield, via the o-quinodimethane 8, the endoperoxyde 9 by simple reaction with molecular oxygen. By contrast, 1 with 2,3-dichloro-1,4-naphthoquinone gives the tetracyclic compound 7 by a double [2 + 4] cycloaddition between the Ge=C double bond and the conjugated system O=C-CH=CH. The new steric demanding germene Mes(2)Ge=CR2' 5 (CR2' = 2,7-di-tert-butylfluorenylidene) undergoes similar [2 + 4] cycloadditions with various substituted or unsubstituted naphthoquinones, leading to tetracyclic adducts 10-12. The germene 5, the endoperoxide 9 and the cycloadducts 10 and 12 have been structurally characterized.
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