Journal
DALTON TRANSACTIONS
Volume 39, Issue 9, Pages 2423-2427Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b924783c
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- French Government
- ARKEMA
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The reaction of tin dichloride with catalytically-relevant group 10 metal precursors [M(Cl)(X)(2-PyPPh2)(2)] (M = Ni, Pd, Pt; 2-PyPPh2 = 2-pyridyldiphenylphosphine; X = Cl, Me) provides easy access to unprecedented cationic dichlorostannylene complexes [M(X)(2-PyPPh2)(2)(SnCl2)](+) where the M-Sn bond is bridged by two head-to-head coordinated 2-PyPPh2 ligands. The formation of such species instead of the classical neutral trichlorostannyl derivatives [M(X)(SnCl3)(2-PyPPh2)(2)] offers a new insight on the specific effect of the SnCl2 cocatalyst in group 10 metal catalyzed transformations.
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