Journal
DALTON TRANSACTIONS
Volume 39, Issue 12, Pages 2995-2997Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b924915j
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology, Japan [18GS0207, 18065013]
- MEXT, Japan [B08]
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The dinuclear Ni(II)-Ni(I) complex Ni-II(dadt(Et))Ni-I(SDmp)(PPh3) was synthesized as a Ni(II)(d)-Ni(I)(p) model of the Acluster in acetyl CoA synthase. This complex was reacted with Co(dmgBF(2))(2)(Me)(Py) and KSDmp successively to afford Ni(dadt(Et))Ni(Me)(SDmp), which further reacts with CO to afford the acetylthioester CH3C(O)SDmp via reductive elimination.
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