Journal
DALTON TRANSACTIONS
Volume 39, Issue 15, Pages 3543-3553Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b920389c
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Funding
- Boston University
- National Science Foundation [NSF-CCF 829890, NSF-REU 0649114, NSF-CHE 0619339]
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This Perspective highlights our efforts to assemble infinite chains of metal atoms in double salts of the form [M](+)[M](-) under the complementary influences of metallophilic interactions and electrostatic attraction. Our design strategy necessarily incorporates the significant steric constraints of one-dimensional assemblies as well as the more subtle and challenging electronic tuning of weak dispersion forces.
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