4.7 Article

A robust hydrophilic pyridine-bridged bis-benzimidazolylidene palladium pincer complex: Synthesis and its catalytic application towards Suzuki-Miyaura couplings in aqueous solvents

Journal

DALTON TRANSACTIONS
Volume 39, Issue 44, Pages 10598-10600

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt01083a

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Funding

  1. Fudan University
  2. National Science Foundation of China [20902011]
  3. Shanghai Municipal Science and Technology Commission [10QA1400500]
  4. Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Department of Chemistry, Fudan University [2010MCIMKF04]

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A novel hydrophilic pyridine-bridged bis-benzimidazolylidene palladium pincer complex (3) acted as a highly efficient robust recyclable molecular catalyst towards Suzuki-Miyaura coupling reactions in aqueous media and tolerated various functional groups (even heterocycles) with extremely low catalyst loading.

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