Journal
DALTON TRANSACTIONS
Volume 39, Issue 21, Pages 5074-5076Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt00152j
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Funding
- Royal Society
- EPSRC
- European Research Council
- University of Nottingham
- UK National Nuclear Laboratory
- Engineering and Physical Sciences Research Council [EP/F030517/1] Funding Source: researchfish
- EPSRC [EP/F030517/1] Funding Source: UKRI
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Treatment of H2C(PPh(2)NMes)(2) (1, Mes = 2,4,6-Me3C6H2) with two equivalents of (BuLi)-Li-t afforded the methandiide complex [Li-2{C(PPh(2)NMes)(2)}(2)](2) (2); reaction of 2 with [UI3(THF)(4)] gave [U{C(PPh(2)NMes)(2)}(2)] (3), which is the first homoleptic uranium bis(carbene) complex with two formal U=C double bonds.
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